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Experiments

  300 MHz500 MHz600 MHz
1H proton NMRYesYesYes
13C-{1H} proton decoupled carbon NMRYesYesYes
11BBor NMRYes??
15N-{1H} protonen decoupled 15N-NMR
Only after prior discussion!
NoNoYes
19F-{1H}proton decoupled Fluor NMRYes?Yes
19FFluor NMRYes?Yes
29Si-{1H} proton decoupled silizium NMR
Only after prior discusssion!
NoNoYes
31P-{1H}proton decoupled phosphor NMRYes?Yes
31Pphosphor NMRYes?Yes
77Se-{1H}proton decoupled selen NMRNoNoYes
  300 MHz500 MHz600 MHz
water
supression
proton NMR with suppressed water signal??Yes
selective TOCSY A selective TOSCY allows under certain conditions splitting of a proton spectrum in several subspectra.
Only after prior discussion!
NoNoYes
selective decoupledOne nucleus is selectively decoupledNoNoYes
  300 MHz500 MHz600 MHz
DEPT-45only protonated carbonsYes?Yes
DEPT-90only CH carbonsYes?Yes
DEPT-135only protonated carbons:
CH, CH3 positiv, CH2 negativ
Yes?Yes
13C gated decoupledA proton coupled carbon NMR. The signal enhancement due to NOE is utilised.Yes?Yes
inverse decoupledprotonen decoupled carbon NMR with intact integrationYes?Yes
  300 MHz500 MHz600 MHz
COSYprotonen-protonen-correlation, sensitive for a 3J-couplingYesYesYes
TOCSYcross peaks for all protons in the same spin-systemNo?Yes
NOESYprotonen-protonen-correlation, sensitive to the distance of the atomsYes?Yes
ROESYprotonen-protonen-correlation, sensitive to the distance of the atoms, replaces NOESY for molecular weigths between 1000 and 3000Yes?Yes
  300 MHz500 MHz600 MHz
HSQC, HMQCprotonen-carbon-correlation, sensitive for 1J-couplingYesYesYes
HMBCprotonen-carbon-correlation, sensitive for 2J- and 3J-couplingYesYesYes
HETCORsimilar to HSQC or HMBC, but the FID of carbon is meassured => longer aquisition time, but a higher resolution on the 13C-axisYes?Yes
  300 MHz500 MHz600 MHz
1H-15N-HMBC 1H-15N-Correlation NoNoYes
1H-31P-HMBC 1H-31P-Correlation NoNoYes
1H-77Se-HMBC 1H-77Se-Correlation NoNoYes
1H-19F-HOESY1H-19F-Hetero-NOESYNoNoYes
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